Bis(1-adamantylammonium) hexafluoridogermanate
نویسندگان
چکیده
The title compound, (C(10)H(18)N)(2)[GeF(6)], was obtained hydro-thermally from an aqueous solution of GeO(2), H(3)BO(3), NiCl(2), adamantylammonium chloride, butanol and hydro-fluoric acid. The structure consists of discrete bis(1-adamantylammonium) cations lying on crystallographic mirror planes and hexa-fluoridogermanate anions disordered about sites of 2/m point symmetry. In the latter, the Ge atom lies on the site of 2/m symmetry, one F atom lies on the mirror plane and two further F atoms are included in general positions with 50% site occupancy. The cations and anions lie in layers with N-H⋯F hydrogen bonds formed between them.
منابع مشابه
Bis(1-adamantylammonium) tetrachloridocobaltate(II)
The Co(II) atom in the title salt, (C(10)H(18)N)(2)[CoCl(4)], exists in a tetra-hedral coordination geometry. The asymmetric unit has two cations that lie on different special positions of site symmetry m; the anion lies on another special position of site symmetry m.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007